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Assessing the Impact of Molten Halide Salts on Creep of Structural Alloys at 650°-750°C

by Rishi R Pillai, Bruce A Pint
Publication Type
Conference Paper
Book Title
Advances in Materials Technology for Power Plants
Publication Date
Page Numbers
897 to 908
Volume
84871
Publisher Location
United States of America
Conference Name
10th International Conference on Advances in Materials, Manufacturing & Repair for Power Plants
Conference Location
Bonita Springs, Florida, United States of America
Conference Sponsor
EPRI, ASM
Conference Date
-

There is a critical lack of data on the mechanical behavior of candidate structural materials for advanced nuclear reactors under molten halide salt environments. Limited legacy data from the molten salt reactor experiment (MSRE) program showed a significant reduction in creep rupture strength of a Ni-base alloy in molten fluoride salt. With ongoing efforts to commercialize different molten salt reactor concepts, the industry can considerably benefit from quantitative information on the impact of molten halide salts on the engineering properties such as creep and fatigue strength of materials of interest. The present work aims to assess the role of molten salt corrosion on the creep behavior of three alloys 316H, 617 and 282 at 650-816 °C. Creep tests were conducted in fluoride (FLiNaK) and chloride (NaCl-MgCl2) salts. Initial results from the ongoing testing will be presented which suggest that the molten salt environment caused a 25-50% reduction in creep rupture lifetime compared to air exposures. Physics-based corrosion and creep models were employed to gain some insights into the potential degradation mechanisms.