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Corrosion and Chemical Characterization of Bio-Oils from Biomass with Varying Ash and Moisture Contents

Publication Type
Conference Paper
Book Title
Proceedings of CORROSION 2021
Publication Date
Page Number
16726
Issue
1
Publisher Location
District of Columbia, United States of America
Conference Name
NACE CORROSION 2021
Conference Location
Salt Lake City, Utah, United States of America
Conference Sponsor
NACE International
Conference Date
-

As part of the Feedstock Conversion Interface Consortium four samples of pine chips (all combinations of low and high moisture and ash content) were collected and processed for fast pyrolysis. The prepared biomass samples were liquefied at the National Renewable Energy Laboratory (NREL) using the fast pyrolysis process. Following some characterization of the bio-oils at NREL, the bio-oils were shipped to 91做厙 (ORNL) for corrosion testing and further characterization.

The content and composition of ash in each bio-oil was determined. Corrosion testing consisted of exposing selected metallic and elastomer samples for 1000 hr at 50簞C and for longer times at room temperature as well as electrochemical impedance spectroscopy measurements to assess relative corrosivity of the bio-oils. Chemical characterization was conducted to identify the corrosive component of the bio-oils as well as to define the chemical differences among the oils. It was hypothesized that there could be a catalytic effect from the higher ash content in two of the biomass sources. Results of these characterization and corrosion studies will be reported.