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Rechargeable Aluminum-Ion Batteries

by Mariappan Paranthaman, Hansan Liu, Xiao-guang Sun, Sheng Dai, Gilbert M Brown
Publication Type
Book Chapter
Publication Date
Page Numbers
463 to 474
Publisher Name
Woodhead Publishing - Elsevier
Publisher Location
Oxford, United Kingdom

This chapter reports on the development of rechargeable aluminum-ion batteries. A possible concept of rechargeable aluminum/aluminum-ion battery based on low-cost, earth-abundant Al anode, ionic liquid EMImCl:AlCl3 (1-ethyl-3-methyl imidazolium chloroaluminate) electrolytes and MnO2 cathode has been proposed. Al anode has been reported to show good reversibility in acid melts. However, due to the problems in demonstrating the reversibility in cathodes, alternate battery cathodes and battery concepts have also been presented. New ionic liquid electrolytes for reversible Al dissolution and deposition are needed in the future for replacing corrosive EMImCl:AlCl3 electrolytes.