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This invention utilizes a custom-synthesized vinyl trifluoromethanesulfonimide (VTFSI) salt and an alcohol containing small molecule or polymer for the synthesis of novel single-ion conducting polymer electrolytes for the use in Li-ion and beyond Li-ion batteries, fuel cells,

This invention utilizes a salt and an amine containing small molecule or polymer for the synthesis of a bulky anionic salt or containing single-ion conducting polymer electrolyte for the use in Li-ion and beyond Li-ion batteries.