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Mechanically Robust Ion-Conducting Membranes for Redox Flow Batteries

Topic:

Invention Reference Number

201804195
Redox flow battery membrane

This invention exceptionally improves the mechanical strength of PEO-, or poly(ethylene oxide), based solid polymer electrolytes without sacrificing ionic conductivity. This new conductive membrane’s demonstrated shear modulus, a measure of a material’s ability to resist transverse deformations, reaches 2.5 gigapascals, which is at least two orders of magnitude higher than other PEO-based electrolyte counterparts over a broad temperature range. The maximum conductivity is also improved over most PEO-based electrolytes.

Because the shear modulus of the cross-linked PEO-glass fiber composite is close to that of lithium metal, it is expected to dramatically inhibit lithium dendrite growth, which leads to catastrophic failure in lithium metal batteries.

Benefits

  • Improved ionic conductivity
  • Improved abilities for fabrication
  • Exceptionally high shear modulus
  • Higher mechanical strength
  • Dimensional stability

Applications and Industries

  • Membranes for redox flow batteries
  • Separators for battery chemistries
  • Membranes for water desalination

Contact

To learn more about this technology, email partnerships@ornl.gov or call 865-574-1051.