Synthesis: We perform precise synthesis of functional polymers with special emphasis on polymerization, selective deuteration, small molecule synthesis, and ionic polymerization, as well as macromolecular characterization. We utilize the best high yielding and controlled reaction condition including the use of Schlenk lines, glass blown custom-made reactors, autosamplers, and flow chemistry reaction methods including online monitoring. In collaboration with the theory group, we are able to focus on modeling and quantum chemical calculations (atomistic to coarse-grain) to predict the best reactivities and desirable properties prior to the reaction.
The monomers shown below are readily available with a lead time of 8-12 weeks and can be requested with a CNMS rapid access proposal to support neutron scattering studies at SNS and HFIR. The monomers will be at ≥90% chemical purity (remainder being trace solvent), and will be inhibited with 50-100 ppm MEHQ or Hydroquinone. Custom deuterated monomer synthesis needs to be requested through general CNMS proposal calls and will typically have longer lead times.
